The key role of major and trace elements in the formation of five common urinary stones.


Journal

BMC urology
ISSN: 1471-2490
Titre abrégé: BMC Urol
Pays: England
ID NLM: 100968571

Informations de publication

Date de publication:
30 May 2024
Historique:
received: 09 01 2024
accepted: 10 05 2024
medline: 31 5 2024
pubmed: 31 5 2024
entrez: 30 5 2024
Statut: epublish

Résumé

Urolithiasis has emerged as a global affliction, recognized as one of the most excruciating medical issues. The elemental composition of stones provides crucial information, aiding in understanding the causes, mechanisms, and individual variations in stone formation. By understanding the interactions between elements in various types of stones and exploring the key role of elements in stone formation, insights are provided for the prevention and treatment of urinary stone disease. This study collected urinary stone samples from 80 patients in Beijing. The chemical compositions of urinary stones were identified using an infrared spectrometer. The concentrations of major and trace elements in the urinary stones were determined using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS), respectively. The data were processed using correlation analysis and Principal Component Analysis (PCA) methods. Urinary stones are categorized into five types: the calcium oxalate (CO) stone, carbonate apatite (CA) stone, uric acid (UA) stone, mixed CO and CA stone, and mixed CO and UA stone. Ca is the predominant element, with an average content ranging from 2.64 to 27.68% across the five stone groups. Based on geochemical analysis, the high-content elements follow this order: Ca > Mg > Na > K > Zn > Sr. Correlation analysis and PCA suggested significant variations in the interactions between elements for different types of urinary stones. Trace elements with charges and ionic structures similar to Ca may substitute for Ca during the process of stone formation, such as Sr and Pb affecting the Ca in most stone types except mixed stone types. Moreover, the Mg, Zn and Ba can substitute for Ca in the mixed stone types, showing element behavior dependents on the stone types. This study primarily reveals distinct elemental features associated with five types of urinary stones. Additionally, the analysis of these elements indicates that substitutions of trace elements with charges and ion structures similar to Ca (such as Sr and Pb) impact most stone types. This suggests a dependence of stone composition on elemental behavior. The findings of this study will enhance our ability to address the challenges posed by urinary stones to global health and improve the precision of interventions for individuals with different stone compositions.

Sections du résumé

BACKGROUND BACKGROUND
Urolithiasis has emerged as a global affliction, recognized as one of the most excruciating medical issues. The elemental composition of stones provides crucial information, aiding in understanding the causes, mechanisms, and individual variations in stone formation. By understanding the interactions between elements in various types of stones and exploring the key role of elements in stone formation, insights are provided for the prevention and treatment of urinary stone disease.
METHODS METHODS
This study collected urinary stone samples from 80 patients in Beijing. The chemical compositions of urinary stones were identified using an infrared spectrometer. The concentrations of major and trace elements in the urinary stones were determined using Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and Inductively Coupled Plasma Mass Spectrometry (ICP-MS), respectively. The data were processed using correlation analysis and Principal Component Analysis (PCA) methods.
RESULTS RESULTS
Urinary stones are categorized into five types: the calcium oxalate (CO) stone, carbonate apatite (CA) stone, uric acid (UA) stone, mixed CO and CA stone, and mixed CO and UA stone. Ca is the predominant element, with an average content ranging from 2.64 to 27.68% across the five stone groups. Based on geochemical analysis, the high-content elements follow this order: Ca > Mg > Na > K > Zn > Sr. Correlation analysis and PCA suggested significant variations in the interactions between elements for different types of urinary stones. Trace elements with charges and ionic structures similar to Ca may substitute for Ca during the process of stone formation, such as Sr and Pb affecting the Ca in most stone types except mixed stone types. Moreover, the Mg, Zn and Ba can substitute for Ca in the mixed stone types, showing element behavior dependents on the stone types.
CONCLUSION CONCLUSIONS
This study primarily reveals distinct elemental features associated with five types of urinary stones. Additionally, the analysis of these elements indicates that substitutions of trace elements with charges and ion structures similar to Ca (such as Sr and Pb) impact most stone types. This suggests a dependence of stone composition on elemental behavior. The findings of this study will enhance our ability to address the challenges posed by urinary stones to global health and improve the precision of interventions for individuals with different stone compositions.

Identifiants

pubmed: 38816700
doi: 10.1186/s12894-024-01498-5
pii: 10.1186/s12894-024-01498-5
doi:

Substances chimiques

Trace Elements 0
Calcium Oxalate 2612HC57YE
Uric Acid 268B43MJ25

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

114

Subventions

Organisme : Fundamental Research Funds for the Central Universities
ID : 2652023001
Organisme : National Natural Science Foundation of China
ID : No. 41661144029

Informations de copyright

© 2024. The Author(s).

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Auteurs

Yu Tian (Y)

Department of Urology, Peking University Third Hospital, Beijing, 100191, China.

Guilin Han (G)

Institute of Earth Sciences, China University of Geosciences, No. 29 Xueyuan Road, Haidian District, Beijing, 100083, China. hanguilin@cugb.edu.cn.
Frontiers Science Center for Deep-time Digital Earth, Institute of Earth Sciences, China University of Geosciences, Beijing, 100083, China. hanguilin@cugb.edu.cn.

Shudong Zhang (S)

Department of Urology, Peking University Third Hospital, Beijing, 100191, China. zhangshudong@bjmu.edu.cn.

Ziyang Ding (Z)

Institute of Earth Sciences, China University of Geosciences, No. 29 Xueyuan Road, Haidian District, Beijing, 100083, China.
Frontiers Science Center for Deep-time Digital Earth, Institute of Earth Sciences, China University of Geosciences, Beijing, 100083, China.

Rui Qu (R)

Institute of Earth Sciences, China University of Geosciences, No. 29 Xueyuan Road, Haidian District, Beijing, 100083, China.
Frontiers Science Center for Deep-time Digital Earth, Institute of Earth Sciences, China University of Geosciences, Beijing, 100083, China.

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