Oxidation Study of Oleocanthal and Oleacein Induced by Oxone.

Oxidation-Reduction Aldehydes / chemistry Olive Oil / chemistry Antioxidants / chemistry Phenols / chemistry Furans / chemistry Cyclopentane Monoterpenes / chemistry

Journal

Planta medica
ISSN: 1439-0221
Titre abrégé: Planta Med
Pays: Germany
ID NLM: 0066751

Informations de publication

Date de publication:
Jun 2024
Historique:
medline: 7 6 2024
pubmed: 7 6 2024
entrez: 6 6 2024
Statut: ppublish

Résumé

A selective Oxone-induced oxidation of oleocanthal and oleacein, the two main secoiridoids of olive oil, to their bis-oxidized products is described. This protocol is based on a Baeyer-Villiger mechanism and the concentration of Oxone in the final solution. The bis-oxidation of the aldehydic compounds could be extended for the synthesis of various semisynthetic analogs. The obtained acids exhibit strong antioxidant activity, being efficient free radical scavengers.

Identifiants

DOI: 10.1055/a-2235-0009 PMID: 38843795
pubmed: 38843795
doi: 10.1055/a-2235-0009
doi:

Substances chimiques

oleocanthal AC7QO6038O
oleacein 0
Aldehydes 0
Olive Oil 0
Antioxidants 0
Phenols 0
Furans 0
Cyclopentane Monoterpenes 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

554-560

Subventions

Organisme : Hellenic Foundation for Research and Innovation (HFRI) under the 3rd Call for HFRI PhD Fellowships (Fellowship Number: 5266)
ID : Fellowship Number: 5266
Organisme : European Regional Development Fund of the European Union and Greek national funds through the Operational Program Competitiveness, Entrepreneurship and Innovation, under the call RESEARCH -CREATE -INNOVATE (project code: T2EDK-02423)
ID : project code: T2EDK-02423

Informations de copyright

Thieme. All rights reserved.

Déclaration de conflit d'intérêts

The authors declare that they have no conflict of interest.

Auteurs

Lemonia Antoniadi (L)

Division of Pharmacognosy and Natural Products Chemistry, Department of Pharmacy, National and Kapodistrian University of Athens, Panepistimioupoli Zografou, Athens, Greece.

Apostolis Angelis (A)

Division of Pharmacognosy and Natural Products Chemistry, Department of Pharmacy, National and Kapodistrian University of Athens, Panepistimioupoli Zografou, Athens, Greece.

Ioannis K Kostakis (IK)

Division of Pharmaceutical Chemistry, Department of Pharmacy, National and Kapodistrian University of Athens, Panepistimioupoli Zografou, Athens, Greece.

Leandros A Skaltsounis (LA)

Division of Pharmacognosy and Natural Products Chemistry, Department of Pharmacy, National and Kapodistrian University of Athens, Panepistimioupoli Zografou, Athens, Greece.

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Classifications MeSH

questionsmedicales.fr › Métabolisme › Métabolisme énergétique › Oxydoréduction › Oxidation Study of Oleocanthal and Oleacein...
questionsmedicales.fr › Composés chimiques organiques › Aldéhydes › Oxidation Study of Oleocanthal and Oleacein...
questionsmedicales.fr › Aliments et boissons › Aliments › Matières grasses alimentaires › Matières grasses alimentaires insaturées › Huile d'olive › Oxidation Study of Oleocanthal and Oleacein...
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Agents protecteurs › Antioxydants › Oxidation Study of Oleocanthal and Oleacein...
questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures cycliques › Hydrocarbures aromatiques › Dérivés du benzène › Phénols › Oxidation Study of Oleocanthal and Oleacein...
questionsmedicales.fr › Composés hétérocycliques › Composés hétéromonocycliques › Furanes › Oxidation Study of Oleocanthal and Oleacein...
questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Terpènes › Monoterpènes › Cyclopentane monoterpenes › Oxidation Study of Oleocanthal and Oleacein...