Synthesis of novel N-substituted tetrabromophthalic as corrosion inhibitor and its inhibition of microbial influenced corrosion in cooling water system.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
25 Oct 2024
Historique:
received: 15 07 2024
accepted: 11 10 2024
medline: 26 10 2024
pubmed: 26 10 2024
entrez: 25 10 2024
Statut: epublish

Résumé

This study investigates the efficacy of newly synthesized inhibitor with a dual function of corrosion inhibition and biocide for control of microbial influenced corrosion (MIC) in carbon steel API 5LX in the cooling tower water (CTW) environment. Four types of N-substituted tetrabromophthalic inhibitor (N-TBI) were synthesized, and the structural characterization was performed via proton nuclear magnetic resonance spectroscopy, thermogravimetric analysis and high-resolution mass spectrometry. These studies revealed the distinctive optical, thermal, and dielectric properties of the synthesized inhibitors. The corrosion inhibition efficiency has been evaluated by the weight loss (WL) analysis and electrochemical measurements (ECM) and biofilm assay. Biofilm assays and WL showed that inhibitor II exhibited the highest inhibition efficiency 74% and 79% respectively than others. Further ECM showed that the higher charge transfer resistance and the lower corrosion current, suggesting a protective film formed on the metal surface which was due to the adsorption of the N-TBI. Fourier transform infrared spectroscopy confirmed the adsorption of the N-TBI as C-O stretching and C-H bending with the Fe complex. X-ray diffractometer revealed that the presence of inhibitors in the corrosion product (Fe

Identifiants

pubmed: 39455801
doi: 10.1038/s41598-024-76254-8
pii: 10.1038/s41598-024-76254-8
doi:

Substances chimiques

Phthalic Acids 0
Steel 12597-69-2
Water 059QF0KO0R

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

25408

Informations de copyright

© 2024. The Author(s).

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Auteurs

Krishnan Vignesh (K)

Environmental Molecular Microbiology Research Laboratory, Department of Biotechnology, Thiruvalluvar University, Serkadu, Vellore, Tamil Nadu, 632115, India.

Sankar Sujithra (S)

Department of Chemistry, School of Physical and Chemical Sciences, B S Abdur Rahman Crescent Institute of Science and Technology, Vandalur, Chennai, 600 048, India.

Murugesan Vajjiravel (M)

Department of Chemistry, School of Physical and Chemical Sciences, B S Abdur Rahman Crescent Institute of Science and Technology, Vandalur, Chennai, 600 048, India.

Jayaraman Narenkumar (J)

Department of Environmental and Water Resources Engineering, School of Civil Engineering, Vellore Institute of Technology, Vellore, Tamil Nadu, India.

Bhaskar Das (B)

Department of Environmental and Water Resources Engineering, School of Civil Engineering, Vellore Institute of Technology, Vellore, Tamil Nadu, India.

Mohamad S AlSalhi (MS)

Department of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia.

Sandhanasamy Devanesan (S)

Department of Physics and Astronomy, College of Science, King Saud University, P.O. Box 2455, 11451, Riyadh, Saudi Arabia.

Aruliah Rajasekar (A)

Environmental Molecular Microbiology Research Laboratory, Department of Biotechnology, Thiruvalluvar University, Serkadu, Vellore, Tamil Nadu, 632115, India. rajasekargood@gmail.com.

Tabarak Malik (T)

Department of Biomedical Sciences, Institute of Health, Jimma University, Jimma, Ethiopia. tabarak.malik@ju.edu.et.
Division of Research and Development, Lovely Professional University, Phagwara, 144411, Punjab , India. tabarak.malik@ju.edu.et.

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