Lewis Acid Coordination Redirects S-Nitrosothiol Signaling Output.
S-nitrosothiols
bioinorganic chemistry
lewis acids
nitric oxide
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
26 06 2020
26 06 2020
Historique:
received:
28
01
2020
pubmed:
25
2
2020
medline:
18
3
2021
entrez:
25
2
2020
Statut:
ppublish
Résumé
S-Nitrosothiols (RSNOs) serve as air-stable reservoirs for nitric oxide in biology. While copper enzymes promote NO release from RSNOs by serving as Lewis acids for intramolecular electron-transfer, redox-innocent Lewis acids separate these two functions to reveal the effect of coordination on structure and reactivity. The synthetic Lewis acid B(C
Identifiants
pubmed: 32090399
doi: 10.1002/anie.202001450
pmc: PMC7385465
mid: NIHMS1611670
doi:
Substances chimiques
Lewis Acids
0
S-Nitrosothiols
0
Nitric Oxide
31C4KY9ESH
Types de publication
Journal Article
Research Support, N.I.H., Extramural
Research Support, U.S. Gov't, Non-P.H.S.
Langues
eng
Sous-ensembles de citation
IM
Pagination
10854-10858Subventions
Organisme : NIGMS NIH HHS
ID : R01 GM126205
Pays : United States
Informations de copyright
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
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