Synthesis and characterization of poly(N-isopropylmethacrylamide-acrylic acid) smart polymer microgels for adsorptive extraction of copper(II) and cobalt(II) from aqueous medium: kinetic and thermodynamic aspects.
Heavy metals
Kinetics
Microgels
Thermodynamics
Toxicity
Journal
Environmental science and pollution research international
ISSN: 1614-7499
Titre abrégé: Environ Sci Pollut Res Int
Pays: Germany
ID NLM: 9441769
Informations de publication
Date de publication:
Aug 2020
Aug 2020
Historique:
received:
02
01
2020
accepted:
30
04
2020
pubmed:
18
5
2020
medline:
11
7
2020
entrez:
17
5
2020
Statut:
ppublish
Résumé
Extraction of toxic heavy metal ions from aqueous medium using poly(N-isopropylmethacrylamide-acrylic acid) (P(NiPmA-Ac)) microgels as adsorbent has been investigated in present study. P(NiPmA-Ac) microgel particles were prepared by free radical precipitation polymerization in aqueous medium. Morphology and size of the prepared microgel particles was investigated by transmission electron microscopy (TEM). The Fourier transform infrared (FT-IR) analysis of pure and metal ion-loaded microgel particles was performed to confirm the presence of various functionalities of microgel particles and their interaction with metal ions extracted from aqueous medium. Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were used to investigate the thermal stability and thermal behavior of pure and metal ion-loaded microgel particles. Contents of metal ions loaded into microgel particles were determined by TGA analysis. It was observed that P(NiPmA-Ac) particles have a potential to extract Cu
Identifiants
pubmed: 32415448
doi: 10.1007/s11356-020-09145-w
pii: 10.1007/s11356-020-09145-w
doi:
Substances chimiques
Acrylates
0
Microgels
0
Stimuli Responsive Polymers
0
Water Pollutants, Chemical
0
Cobalt
3G0H8C9362
Copper
789U1901C5
acrylic acid
J94PBK7X8S
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
28169-28182Subventions
Organisme : Higher Education Commision, Pakistan
ID : No.20-3995/NRPU/R&D/HEC/14/1212
Organisme : University of the Punjab
ID : No:/503/EST.I
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