Activation of Ligand Reaction on an Iron Complex: H/D Exchange Reaction of a Low-Spin Bis[2-(Pyridylmethylidene)-1-(2-pyridyl)methylamine]iron(II) Complex.

Coordination Complexes / chemical synthesis Deuterium Exchange Measurement Ethylamines / chemistry Ferrous Compounds / chemistry Magnetic Resonance Spectroscopy Molecular Conformation Quantum Theory
2,6-dimethylpyridine acetonitrile-d3 deuterium oxide hydrogen–deuterium exchange reaction iron complex

Journal

Chemical & pharmaceutical bulletin
ISSN: 1347-5223
Titre abrégé: Chem Pharm Bull (Tokyo)
Pays: Japan
ID NLM: 0377775

Informations de publication

Date de publication:
2020
Historique:
entrez: 4 8 2020
pubmed: 4 8 2020
medline: 5 2 2021
Statut: ppublish

Résumé

With the aim of shedding some light on the still scarcely investigated mechanism of transformation of imines in metal complexes, this study describes the investigation of the hydrogen-deuterium (H/D) exchange reaction of a bis[2-(pyridylmethylidene)-1-(2-pyridylmethylamine]iron(II) complex ([Fe(PMAP)

Identifiants

DOI: 10.1248/cpb.c20-00383 PMID: 32741911
pubmed: 32741911
doi: 10.1248/cpb.c20-00383
doi:

Substances chimiques

Coordination Complexes 0
Ethylamines 0
Ferrous Compounds 0
ethylamine YG6MGA6AT5

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

713-716

Auteurs

Masanori Imai (M)

College of Pharmacy, Kinjo Gakuin University.

Koichi Kato (K)

College of Pharmacy, Kinjo Gakuin University.

Yoshihiro Yamaguchi (Y)

Environmental Safety Center, Kumamoto University.

Mikako Fujita (M)

Medicinal and Biological Chemistry Science Farm Joint Research Laboratory, Faculty of Life Sciences, Kumamoto University.

Masami Otsuka (M)

Medicinal and Biological Chemistry Science Farm Joint Research Laboratory, Faculty of Life Sciences, Kumamoto University.
Department of Drug Discovery, Science Farm Ltd.

Hiromasa Kurosaki (H)

College of Pharmacy, Kinjo Gakuin University.

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Complexes de coordination › Activation of Ligand Reaction on an Iron...
questionsmedicales.fr › Techniques d'investigation › Techniques de chimie analytique › Mesure d'échange de deutérium › Activation of Ligand Reaction on an Iron...
questionsmedicales.fr › Composés chimiques organiques › Amines › Éthylamines › Activation of Ligand Reaction on an Iron...
questionsmedicales.fr › Produits chimiques inorganiques › Composés du fer › Composés du fer II › Activation of Ligand Reaction on an Iron...
questionsmedicales.fr › Techniques d'investigation › Techniques de chimie analytique › Analyse spectrale › Spectroscopie par résonance magnétique › Activation of Ligand Reaction on an Iron...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes biochimiques › Conformation moléculaire › Activation of Ligand Reaction on an Iron...
questionsmedicales.fr › Disciplines des sciences naturelles › Physique › Physique nucléaire › Théorie quantique › Activation of Ligand Reaction on an Iron...