Enantioselective Lactonization by π-Acid-Catalyzed Allylic Substitution: A Complement to π-Allylmetal Chemistry.


Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
04 10 2021
Historique:
received: 23 06 2021
pubmed: 24 8 2021
medline: 17 11 2021
entrez: 23 8 2021
Statut: ppublish

Résumé

Asymmetric allylic alkylation (AAA) is a powerful method for the formation of highly useful, non-racemic allylic compounds. Here we present a complementary enantioselective process that generates allylic lactones via π-acid catalysis. More specifically, a catalytic enantioselective dehydrative lactonization of allylic alcohols using a novel Pd

Identifiants

pubmed: 34423520
doi: 10.1002/anie.202108336
doi:

Substances chimiques

Allyl Compounds 0
Lactones 0
Ligands 0

Types de publication

Journal Article Research Support, N.I.H., Extramural Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

22224-22229

Subventions

Organisme : national science foundation
ID : CHE-1900299
Organisme : NIH HHS
ID : S10 OD021758-01A1
Pays : United States
Organisme : NIH HHS
ID : S10 OD021758-01A1
Pays : United States

Informations de copyright

© 2021 Wiley-VCH GmbH.

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Auteurs

Arun Raj Kizhakkayil Mangadan (AR)

Florida Center for Heterocyclic Compounds and, Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, FL, 32611, USA.

Ji Liu (J)

Florida Center for Heterocyclic Compounds and, Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, FL, 32611, USA.

Aaron Aponick (A)

Florida Center for Heterocyclic Compounds and, Department of Chemistry, University of Florida, P.O. Box 117200, Gainesville, FL, 32611, USA.

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