Charged pyridinium oximes with thiocarboxamide moiety are equally or less effective reactivators of organophosphate-inhibited cholinesterases compared to analogous carboxamides.


Journal

Journal of enzyme inhibition and medicinal chemistry
ISSN: 1475-6374
Titre abrégé: J Enzyme Inhib Med Chem
Pays: England
ID NLM: 101150203

Informations de publication

Date de publication:
Dec 2022
Historique:
entrez: 23 2 2022
pubmed: 24 2 2022
medline: 22 3 2022
Statut: ppublish

Résumé

The organophosphorus antidotes, so-called oximes, are able to restore the enzymatic function of acetylcholinesterase (AChE) or butyrylcholinesterase (BChE) via cleavage of organophosphate from the active site of the phosphylated enzyme. In this work, the charged pyridinium oximes containing thiocarboxamide moiety were designed, prepared and tested. Their stability and p

Identifiants

pubmed: 35193448
doi: 10.1080/14756366.2022.2041628
pmc: PMC8881075
doi:

Substances chimiques

Cholinesterase Inhibitors 0
Organophosphates 0
Oximes 0
Pyridinium Compounds 0
Sulfhydryl Compounds 0
Acetylcholinesterase EC 3.1.1.7
Butyrylcholinesterase EC 3.1.1.8

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

760-767

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Auteurs

Zuzana Kohoutova (Z)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.

David Malinak (D)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.
Biomedical Research Centre, University Hospital in Hradec Kralove, Hradec Kralove, Czech Republic.

Rudolf Andrys (R)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.

Jana Svobodova (J)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.

Miroslav Psotka (M)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.
Biomedical Research Centre, University Hospital in Hradec Kralove, Hradec Kralove, Czech Republic.

Monika Schmidt (M)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.
Biomedical Research Centre, University Hospital in Hradec Kralove, Hradec Kralove, Czech Republic.

Lukas Prchal (L)

Biomedical Research Centre, University Hospital in Hradec Kralove, Hradec Kralove, Czech Republic.

Kamil Musilek (K)

Faculty of Science, Department of Chemistry, University of Hradec Kralove, Hradec Kralove, Czech Republic.
Biomedical Research Centre, University Hospital in Hradec Kralove, Hradec Kralove, Czech Republic.

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Classifications MeSH