Elucidating the Color of Rosé Wines Using Polyphenol-Targeted Metabolomics.
Multiple Reaction Monitoring—MRM
UHPLC
anthocyanins
chemometrics
color
mass spectrometry
metabolomics
polyphenols
rosé wine
wine
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
17 Feb 2022
17 Feb 2022
Historique:
received:
01
02
2022
revised:
14
02
2022
accepted:
15
02
2022
entrez:
25
2
2022
pubmed:
26
2
2022
medline:
5
3
2022
Statut:
epublish
Résumé
The color of rosé wines is extremely diverse and a key element in their marketing. It is due to the presence of anthocyanins and of additional pigments derived from them and from other wine constituents. To explore the pigment composition and determine its links with color, 268 commercial rosé wines were analysed. The concentration of 125 polyphenolic compounds was determined by a targeted metabolomics approach using ultra high-performance liquid chromatography coupled to triple quadrupole mass spectrometry (UHPLC-QqQ-MS) analysis in the Multiple Reaction Monitoring (MRM) mode and the color characterised by spectrophotometry and CieLab parameters. Chemometrics analysis of the composition and color data showed that although color intensity is primarily determined by polyphenol extraction (especially anthocyanins and flavanols) from the grapes, different color styles correspond to different pigment compositions. The salmon shade of light rosé wines is mostly due to pyranoanthocyanin pigments, resulting from reactions of anthocyanins with phenolic acids and pyruvic acid, a yeast metabolite. Redness of intermediate color wines is related to anthocyanins and carboxypoyranoanthocyanins and that of dark rosé wines to products of anthocyanin reactions with flavanols while yellowness of these wines is associated to oxidation.
Identifiants
pubmed: 35209149
pii: molecules27041359
doi: 10.3390/molecules27041359
pmc: PMC8874620
pii:
doi:
Substances chimiques
Anthocyanins
0
Polyphenols
0
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : CIFRE
ID : CIFRE 2018/1412
Organisme : CASDAR
ID : CASDAR N°18ART1807
Organisme : Conseil Interprofessionnel des vins de Provence
ID : na
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