Direct Asymmetric Reductive Amination of Alkyl (Hetero)Aryl Ketones by an Engineered Amine Dehydrogenase.

Alkyl (Hetero)Aryl Ketones Amine Dehydrogenase Asymmetric Reductive Amination Chiral Amines Directed Evolution

Journal

Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543

Informations de publication

Date de publication:
16 05 2022
Historique:
received: 10 02 2022
pubmed: 15 3 2022
medline: 11 5 2022
entrez: 14 3 2022
Statut: ppublish

Résumé

The direct asymmetric reductive amination of heteroaryl ketones has been a long-standing synthetic challenge. Here we report the engineering of an amine dehydrogenase (AmDH) from Jeotgalicoccus aerolatus for the asymmetric synthesis of chiral α-(hetero)aryl primary amines in excellent conversions (up to 99 %) and enantioselectivities (up to 99 % ee). The best AmDH variant (Ja-AmDH-M3

Identifiants

pubmed: 35285128
doi: 10.1002/anie.202202264
doi:

Substances chimiques

Amines 0
Ketones 0
Oxidoreductases EC 1.-

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202202264

Informations de copyright

© 2022 Wiley-VCH GmbH.

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Auteurs

Weixi Kong (W)

School of Chemical Engineering and Technology, Hebei University of Technology, No. 8 Guangrong Road, Hongqiao District, Tianjin, 300130, China.

Yunting Liu (Y)

School of Chemical Engineering and Technology, Hebei University of Technology, No. 8 Guangrong Road, Hongqiao District, Tianjin, 300130, China.

Chen Huang (C)

School of Chemical Engineering and Technology, Hebei University of Technology, No. 8 Guangrong Road, Hongqiao District, Tianjin, 300130, China.

Liya Zhou (L)

School of Chemical Engineering and Technology, Hebei University of Technology, No. 8 Guangrong Road, Hongqiao District, Tianjin, 300130, China.

Jing Gao (J)

School of Chemical Engineering and Technology, Hebei University of Technology, No. 8 Guangrong Road, Hongqiao District, Tianjin, 300130, China.

Nicholas J Turner (NJ)

Department of Chemistry, University of Manchester, Manchester Institute of Biotechnology, 131 Princess Street, Manchester, M1 7DN, UK.

Yanjun Jiang (Y)

School of Chemical Engineering and Technology, Hebei University of Technology, No. 8 Guangrong Road, Hongqiao District, Tianjin, 300130, China.

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