Visible-Light-Induced, Single-Metal-Catalyzed, Directed C-H Functionalization: Metal-Substrate-Bound Complexes as Light-Harvesting Agents.
Computational Chemistry
C−H Functionalization
Photocatalysis
Rhodium
Ruthenium
Journal
Angewandte Chemie (International ed. in English)
ISSN: 1521-3773
Titre abrégé: Angew Chem Int Ed Engl
Pays: Germany
ID NLM: 0370543
Informations de publication
Date de publication:
01 08 2022
01 08 2022
Historique:
received:
31
01
2022
pubmed:
29
3
2022
medline:
27
7
2022
entrez:
28
3
2022
Statut:
ppublish
Résumé
C-H functionalization represents one of the most rapidly advancing areas in organic synthesis and is regarded as one of the key concepts to minimize the ecological and economic footprint of organic synthesis. The ubiquity and low reactivity of C-H bonds in organic molecules, however, poses several challenges, and often necessitates harsh reaction conditions to achieve this goal, although it is highly desirable to achieve C-H functionalization reactions under mild conditions. Recently, several reports uncovered a conceptually new approach towards C-H functionalization, where a single transition-metal complex can be used as both the photosensitizer and catalyst to promote C-H bond functionalization in the absence of an exogeneous photosensitizer. In this Minireview, we will provide an overview on recent achievements in C-H functionalization reactions, with an emphasis on the photochemical modulation of the reaction mechanism using such catalysts.
Identifiants
pubmed: 35344253
doi: 10.1002/anie.202201743
pmc: PMC9401074
doi:
Substances chimiques
Coordination Complexes
0
Metals
0
Photosensitizing Agents
0
Transition Elements
0
Types de publication
Journal Article
Review
Research Support, Non-U.S. Gov't
Langues
eng
Sous-ensembles de citation
IM
Pagination
e202201743Informations de copyright
© 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.
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