A cyclic divalent N(I) species isoelectronic to carbodiphosphoranes.

Cations Oxidation-Reduction

Journal

Chemical communications (Cambridge, England)
ISSN: 1364-548X
Titre abrégé: Chem Commun (Camb)
Pays: England
ID NLM: 9610838

Informations de publication

Date de publication:
10 May 2022
Historique:
pubmed: 26 4 2022
medline: 14 5 2022
entrez: 25 4 2022
Statut: epublish

Résumé

The formation of a rare type of diphosphazenium cation is described. Its synthesis features a unique oxidative dealkylation of an iminophosphorane-phosphole by a silver(I) salt. DFT study of this compound reveals the low valent character of the N(I) center.

Identifiants

DOI: 10.1039/d2cc01637k PMID: 35466973
pubmed: 35466973
doi: 10.1039/d2cc01637k
doi:

Substances chimiques

Cations 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

5741-5744

Auteurs

Jiaxin Tian (J)

Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS UMR 8182, Université Paris-Saclay, Bâtiment 420, 91405 Orsay cedex, France. vincent.gandon@universite-paris-saclay.fr.

Marie Cordier (M)

Laboratoire de Chimie Moléculaire (LCM), CNRS UMR 9168 Ecole Polytechnique, Institut Polytechnique de Paris, route de Saclay, 91120 Palaiseau, France. audrey.auffrant@polytechnique.edu.

Christophe Bour (C)

Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS UMR 8182, Université Paris-Saclay, Bâtiment 420, 91405 Orsay cedex, France. vincent.gandon@universite-paris-saclay.fr.
ORCID: 0000-0001-6733-5284

Audrey Auffrant (A)

Laboratoire de Chimie Moléculaire (LCM), CNRS UMR 9168 Ecole Polytechnique, Institut Polytechnique de Paris, route de Saclay, 91120 Palaiseau, France. audrey.auffrant@polytechnique.edu.
ORCID: 0000-0001-6952-4775

Vincent Gandon (V)

Institut de Chimie Moléculaire et des Matériaux d'Orsay, CNRS UMR 8182, Université Paris-Saclay, Bâtiment 420, 91405 Orsay cedex, France. vincent.gandon@universite-paris-saclay.fr.
Laboratoire de Chimie Moléculaire (LCM), CNRS UMR 9168 Ecole Polytechnique, Institut Polytechnique de Paris, route de Saclay, 91120 Palaiseau, France. audrey.auffrant@polytechnique.edu.
ORCID: 0000-0003-1108-9410

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Électrolytes › Ions › Cations › A cyclic divalent N(I) species isoelectronic...
questionsmedicales.fr › Métabolisme › Métabolisme énergétique › Oxydoréduction › A cyclic divalent N(I) species isoelectronic...