Selectivity of Oxidizing Agents toward Axial and Equatorial Hydroxyl Groups.

Hydroxyl Radical Molecular Conformation Oxidants Oxidation-Reduction

Journal

The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R

Informations de publication

Date de publication:
15 07 2022
Historique:
pubmed: 2 7 2022
medline: 19 7 2022
entrez: 1 7 2022
Statut: ppublish

Résumé

A total of 16 oxidizing reagents were screened to compare their oxidation selectivities for axial and equatorial hydroxyl moieties using steroidal methyl chenodeoxycholate, methyl deoxycholate, and 4-

Identifiants

DOI: 10.1021/acs.joc.2c00877 PMID: 35775929
pubmed: 35775929
doi: 10.1021/acs.joc.2c00877
doi:

Substances chimiques

Oxidants 0
Hydroxyl Radical 3352-57-6

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

9157-9170

Auteurs

Miroslav Kaspar (M)

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo namesti 2, Prague 166 10, Czech Republic.
Faculty of Sciences, Charles University in Prague, Albertov 6, Prague 128 43, Czech Republic.

Eva Kudova (E)

Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo namesti 2, Prague 166 10, Czech Republic.
ORCID: 0000-0001-7131-5948

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Classifications MeSH

questionsmedicales.fr › Produits chimiques inorganiques › Radical hydroxyle › Selectivity of Oxidizing Agents toward Axial...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes biochimiques › Conformation moléculaire › Selectivity of Oxidizing Agents toward Axial...
questionsmedicales.fr › Actions chimiques et utilisations › Actions toxiques › Noxas › Oxydants › Selectivity of Oxidizing Agents toward Axial...
questionsmedicales.fr › Métabolisme › Métabolisme énergétique › Oxydoréduction › Selectivity of Oxidizing Agents toward Axial...