A multivariate extension to the standard 4σ criterion for comparison of forensic glass evidence.
4σ criterion
Elemental analysis
Ellipsoid method
Forensic glass analysis
LA-ICP-MS
Laser ablation inductively coupled plasma mass spectrometry
Journal
Forensic science international
ISSN: 1872-6283
Titre abrégé: Forensic Sci Int
Pays: Ireland
ID NLM: 7902034
Informations de publication
Date de publication:
Sep 2022
Sep 2022
Historique:
received:
17
01
2022
revised:
07
07
2022
accepted:
10
07
2022
pubmed:
29
7
2022
medline:
24
8
2022
entrez:
28
7
2022
Statut:
ppublish
Résumé
This manuscript presents a more accurate and easy to implement multivariate generalisation of the international standard 4σ forensic glass comparison technique. Many crimes result in glass breaking, and the broken glass found at a crime scene can be important forensic evidence. The chemical composition of this glass can be measured to establish whether it can be distinguished from glass fragments found on a suspect's clothing. The chemical composition can be measured using laser ablation-inductively coupled plasma mass spectrometry. A commonly used method to compare fragments of glass is the 4σ interval criterion. This method, however, compares each element individually and does not take advantage of the multivariate nature of this data. We introduce a multivariate extension to this method, which makes use of the correlation structure between the elements. We demonstrate that this method results in an improvement in the false positive rate, with only a small compromise in the false negative rate. The improvement in false positive rate is desirable as false positives translate to misleading evidence against a potentially innocent defendant. The multivariate generalisation improves accuracy while retaining a similar interpretation, and so is suitable to present in court.
Identifiants
pubmed: 35901586
pii: S0379-0738(22)00216-X
doi: 10.1016/j.forsciint.2022.111386
pii:
doi:
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
111386Informations de copyright
Crown Copyright © 2022. Published by Elsevier B.V. All rights reserved.
Déclaration de conflit d'intérêts
Conflicts of interest The authors declare no conflicts of interest.