A multivariate extension to the standard 4σ criterion for comparison of forensic glass evidence.

4σ criterion Elemental analysis Ellipsoid method Forensic glass analysis LA-ICP-MS Laser ablation inductively coupled plasma mass spectrometry

Journal

Forensic science international
ISSN: 1872-6283
Titre abrégé: Forensic Sci Int
Pays: Ireland
ID NLM: 7902034

Informations de publication

Date de publication:
Sep 2022
Historique:
received: 17 01 2022
revised: 07 07 2022
accepted: 10 07 2022
pubmed: 29 7 2022
medline: 24 8 2022
entrez: 28 7 2022
Statut: ppublish

Résumé

This manuscript presents a more accurate and easy to implement multivariate generalisation of the international standard 4σ forensic glass comparison technique. Many crimes result in glass breaking, and the broken glass found at a crime scene can be important forensic evidence. The chemical composition of this glass can be measured to establish whether it can be distinguished from glass fragments found on a suspect's clothing. The chemical composition can be measured using laser ablation-inductively coupled plasma mass spectrometry. A commonly used method to compare fragments of glass is the 4σ interval criterion. This method, however, compares each element individually and does not take advantage of the multivariate nature of this data. We introduce a multivariate extension to this method, which makes use of the correlation structure between the elements. We demonstrate that this method results in an improvement in the false positive rate, with only a small compromise in the false negative rate. The improvement in false positive rate is desirable as false positives translate to misleading evidence against a potentially innocent defendant. The multivariate generalisation improves accuracy while retaining a similar interpretation, and so is suitable to present in court.

Identifiants

pubmed: 35901586
pii: S0379-0738(22)00216-X
doi: 10.1016/j.forsciint.2022.111386
pii:
doi:

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

111386

Informations de copyright

Crown Copyright © 2022. Published by Elsevier B.V. All rights reserved.

Déclaration de conflit d'intérêts

Conflicts of interest The authors declare no conflicts of interest.

Auteurs

Oliver Lountain (O)

School of Mathematical Sciences, The University of Adelaide, South Australia, Australia.

Jonathan Tuke (J)

School of Mathematical Sciences, The University of Adelaide, South Australia, Australia.

Hayley Brown (H)

Forensic Science South Australia (FSSA), Australia.

Kahlee Redman (K)

Forensic Science South Australia (FSSA), Australia.

Sharon Wilczek (S)

Forensic Science South Australia (FSSA), Australia.

Melissa A Humphries (MA)

School of Mathematical Sciences, The University of Adelaide, South Australia, Australia. Electronic address: melissa.humphries@adelaide.edu.au.

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Classifications MeSH