Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
24 08 2022
24 08 2022
Historique:
pubmed:
13
8
2022
medline:
26
8
2022
entrez:
12
8
2022
Statut:
ppublish
Résumé
We disclose a 1,4,7-triazacyclononane (TACN) ligand featuring an appended boron Lewis acid. Metalation with Cu(I) affords a series of tetrahedral complexes including a boron-capped cuprous hydride. We demonstrate distinct reactivity modes as a function of chemical oxidation: hydride transfer to CO
Identifiants
pubmed: 35960993
doi: 10.1021/jacs.2c02937
pmc: PMC10291504
mid: NIHMS1904032
doi:
Substances chimiques
Lewis Acids
0
Ligands
0
Copper
789U1901C5
Boron
N9E3X5056Q
Types de publication
Journal Article
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.
Research Support, N.I.H., Extramural
Langues
eng
Sous-ensembles de citation
IM
Pagination
15038-15046Subventions
Organisme : NIGMS NIH HHS
ID : R35 GM136360
Pays : United States
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