Capture Instead of Release: Defect-Modulated Radionuclide Leaching Kinetics in Metal-Organic Frameworks.

Kinetics Metal-Organic Frameworks / chemistry Porosity Radioisotopes Zirconium / chemistry

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
07 09 2022
Historique:
pubmed: 27 8 2022
medline: 9 9 2022
entrez: 26 8 2022
Statut: ppublish

Résumé

Comparison of defect-controlled leaching-kinetics modulation of metal-organic frameworks (MOFs) and porous functionalized silica-based materials was performed on the example of a radionuclide and radionuclide surrogate for the first time, revealing an unprecedented readsorption phenomenon. On a series of zirconium-based MOFs as model systems, we demonstrated the ability to capture and retain >99% of the transuranic

Identifiants

DOI: 10.1021/jacs.2c06905 PMID: 36027644
pubmed: 36027644
doi: 10.1021/jacs.2c06905
doi:

Substances chimiques

Metal-Organic Frameworks 0
Radioisotopes 0
Zirconium C6V6S92N3C

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

16139-16149

Auteurs

Kyoung Chul Park (KC)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Corey R Martin (CR)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Gabrielle A Leith (GA)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Grace C Thaggard (GC)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Gina R Wilson (GR)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Brandon J Yarbrough (BJ)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Buddhima K P Maldeni Kankanamalage (BKP)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Preecha Kittikhunnatham (P)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Abhijai Mathur (A)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Isak Jatoi (I)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Mackenzie A Manzi (MA)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Jaewoong Lim (J)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Ingrid Lehman-Andino (I)

Savannah River National Laboratory, Aiken, South Carolina 29808, United States.

Alejandra Hernandez-Jimenez (A)

Savannah River National Laboratory, Aiken, South Carolina 29808, United States.

Jake W Amoroso (JW)

Savannah River National Laboratory, Aiken, South Carolina 29808, United States.

David P DiPrete (DP)

Savannah River National Laboratory, Aiken, South Carolina 29808, United States.

Yuan Liu (Y)

Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611, United States.

Joseph Schaeperkoetter (J)

Kazuo Inamori School of Engineering, Alfred University, Alfred, New York 14802, United States.

Scott T Misture (ST)

Kazuo Inamori School of Engineering, Alfred University, Alfred, New York 14802, United States.
ORCID: 0000-0003-1604-8044

Simon R Phillpot (SR)

Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611, United States.

Shenyang Hu (S)

Pacific Northwest National Laboratory, Richland, Washington 99352, United States.

Yulan Li (Y)

Pacific Northwest National Laboratory, Richland, Washington 99352, United States.
ORCID: 0000-0002-2431-5408

Antoine Leydier (A)

Commissariat à l'Énergie Atomique (CEA), DES, ISEC, DMRC, University Montpellier, Marcoule, BP 17171, 30207 Bagnols-sur-Cèze Cedex, France.

Vanessa Proust (V)

Commissariat à l'Énergie Atomique (CEA), DES, ISEC, DMRC, University Montpellier, Marcoule, BP 17171, 30207 Bagnols-sur-Cèze Cedex, France.

Agnès Grandjean (A)

Commissariat à l'Énergie Atomique (CEA), DES, ISEC, DMRC, University Montpellier, Marcoule, BP 17171, 30207 Bagnols-sur-Cèze Cedex, France.

Mark D Smith (MD)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.

Natalia B Shustova (NB)

Department of Chemistry and Biochemistry, University of South Carolina, 631 Sumter Street, Columbia, South Carolina 29208, United States.
ORCID: 0000-0003-3952-1949

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Classifications MeSH

questionsmedicales.fr › Phénomènes chimiques › Phénomènes biochimiques › Cinétique › Capture Instead of Release: Defect-Modulated...
questionsmedicales.fr › Structures macromoléculaires › Réseaux organométalliques › Capture Instead of Release: Defect-Modulated...
questionsmedicales.fr › Phénomènes physiques › Phénomènes mécaniques › Porosité › Capture Instead of Release: Defect-Modulated...
questionsmedicales.fr › Produits chimiques inorganiques › Isotopes › Radio-isotopes › Capture Instead of Release: Defect-Modulated...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Zirconium › Capture Instead of Release: Defect-Modulated...