Peroxide-Selective Reduction of O

Crown Ethers Esters Ethylene Glycols Ligands Metallocenes Metals / chemistry Methanol Oxidation-Reduction Oxygen / chemistry Peroxides Phosphates Praseodymium Reducing Agents

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
21 09 2022
Historique:
pubmed: 10 9 2022
medline: 24 9 2022
entrez: 9 9 2022
Statut: ppublish

Résumé

Metal peroxides are key species involved in a range of critical biological and synthetic processes. Rare-earth (group III and the lanthanides; Sc, Y, La-Lu) peroxides have been implicated as reactive intermediates in catalysis; however, reactivity studies of isolated, structurally characterized rare-earth peroxides have been limited. Herein, we report the peroxide-selective (93-99% O

Identifiants

DOI: 10.1021/jacs.2c08140 PMID: 36083877
pubmed: 36083877
doi: 10.1021/jacs.2c08140
doi:

Substances chimiques

Crown Ethers 0
Esters 0
Ethylene Glycols 0
Ligands 0
Metallocenes 0
Metals 0
Peroxides 0
Phosphates 0
Reducing Agents 0
aza-18-crown-6 ether 0
Praseodymium NKN7EZA750
Oxygen S88TT14065
Methanol Y4S76JWI15

Types de publication

Journal Article Research Support, Non-U.S. Gov't Research Support, U.S. Gov't, Non-P.H.S.

Langues

eng

Sous-ensembles de citation

IM

Pagination

17295-17306

Auteurs

Matthew J Lueckheide (MJ)

Department of Chemistry, Brown University, Providence, Rhode Island02912, United States.
ORCID: 0000-0003-3590-6112

Mehmed Z Ertem (MZ)

Chemistry Division, Energy & Photon Sciences, Brookhaven National Laboratory, Upton, New York11973, United States.
ORCID: 0000-0003-1994-9024

Michael A Michon (MA)

Department of Chemistry, Brown University, Providence, Rhode Island02912, United States.

Pawel Chmielniak (P)

Department of Chemistry, Brown University, Providence, Rhode Island02912, United States.

Jerome R Robinson (JR)

Department of Chemistry, Brown University, Providence, Rhode Island02912, United States.
ORCID: 0000-0002-9111-3822

Articles similaires

Hemiarthroplasty in young patients.

Hazimah Mahmud, Dong Wang, Andra Topan-Rat et al.
1.00
Humans Male Hemiarthroplasty Middle Aged Aged

A molecular mechanism for bright color variation in parrots.

Roberto Arbore, Soraia Barbosa, Jindich Brejcha et al.
1.00
Animals Feathers Pigmentation Parrots Aldehyde Dehydrogenase

A head-to-head comparison of MM/PBSA and MM/GBSA in predicting binding affinities for the CB

Mei Qian Yau, Clarence W Y Liew, Jing Hen Toh et al.
1.00
Receptor, Cannabinoid, CB1 Ligands Molecular Dynamics Simulation Protein Binding Thermodynamics

Tumor-targeted glutathione oxidation catalysis with ruthenium nanoreactors against hypoxic osteosarcoma.

Hanchen Zhang, Nicolás Montesdeoca, Dongsheng Tang et al.
1.00
Osteosarcoma Animals Glutathione Oxidation-Reduction Mice

Classifications MeSH

questionsmedicales.fr › Composés polycycliques › Composés macrocycliques › Éthers cycliques › Éthers couronnes › Peroxide-Selective Reduction of O
questionsmedicales.fr › Composés chimiques organiques › Acides carboxyliques › Esters › Peroxide-Selective Reduction of O
questionsmedicales.fr › Composés chimiques organiques › Alcools › Glycols › Éthylène glycols › Peroxide-Selective Reduction of O
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Produits chimiques de laboratoire › Ligands › Peroxide-Selective Reduction of O
questionsmedicales.fr › Composés chimiques organiques › Composés organométalliques › Métallocènes › Peroxide-Selective Reduction of O
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Peroxide-Selective Reduction of O
questionsmedicales.fr › Composés chimiques organiques › Alcools › Méthanol › Peroxide-Selective Reduction of O
questionsmedicales.fr › Métabolisme › Métabolisme énergétique › Oxydoréduction › Peroxide-Selective Reduction of O
questionsmedicales.fr › Produits chimiques inorganiques › Gaz › Oxygène › Peroxide-Selective Reduction of O
questionsmedicales.fr › Composés chimiques organiques › Radicaux libres › Peroxydes › Peroxide-Selective Reduction of O
questionsmedicales.fr › Produits chimiques inorganiques › Composés du phosphore › Acides du phosphore › Acides phosphoriques › Phosphates › Peroxide-Selective Reduction of O
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Terres rares › Lanthanides › Praséodyme › Peroxide-Selective Reduction of O
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Produits chimiques de laboratoire › Indicateurs et réactifs › Réducteurs › Peroxide-Selective Reduction of O