Direct Hydroxylarylation of Benzylic Carbons (sp

Benzyl Alcohol Aldehydes Carbon / chemistry Ethanol Catalysis

Journal

The Journal of organic chemistry
ISSN: 1520-6904
Titre abrégé: J Org Chem
Pays: United States
ID NLM: 2985193R

Informations de publication

Date de publication:
06 01 2023
Historique:
pubmed: 24 12 2022
medline: 10 1 2023
entrez: 23 12 2022
Statut: ppublish

Résumé

Diaryl alcohol moieties are widespread in pharmaceuticals. Existing methods for the synthesis of diaryl alcohols require the use of pre-functionalized benzylic alcohols, aromatic aldehydes, or ketones as starting materials. Herein, the first convergent paired electrochemical approach to the direct hydroxylarylation of unactivated benzylic carbons (sp

Identifiants

DOI: 10.1021/acs.joc.2c02363 PMID: 36563045
pubmed: 36563045
doi: 10.1021/acs.joc.2c02363
doi:

Substances chimiques

Benzyl Alcohol LKG8494WBH
Aldehydes 0
Carbon 7440-44-0
Ethanol 3K9958V90M

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

329-340

Auteurs

Xiao-Wen Wang (XW)

Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.

Rui-Xue Li (RX)

Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.

Yang Deng (Y)

Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.

Ming-Qiu-Hao Fu (MQ)

Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.

Ya-Nan Zhao (YN)

Analytical and Testing Center, Southwest University, Chongqing 400715, China.

Zhi Guan (Z)

Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.
ORCID: 0000-0002-0369-6141

Yan-Hong He (YH)

Key Laboratory of Applied Chemistry of Chongqing Municipality, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China.
ORCID: 0000-0002-6405-285X

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures cycliques › Hydrocarbures aromatiques › Dérivés du benzène › Composés benzyliques › Alcools benzyliques › Alcool benzylique › Direct Hydroxylarylation of Benzylic Carbons (sp
questionsmedicales.fr › Composés chimiques organiques › Aldéhydes › Direct Hydroxylarylation of Benzylic Carbons (sp
questionsmedicales.fr › Produits chimiques inorganiques › Éléments › Carbone › Direct Hydroxylarylation of Benzylic Carbons (sp
questionsmedicales.fr › Composés chimiques organiques › Alcools › Éthanol › Direct Hydroxylarylation of Benzylic Carbons (sp
questionsmedicales.fr › Phénomènes chimiques › Catalyse › Direct Hydroxylarylation of Benzylic Carbons (sp