Standoff detection of bacterial spores by field deployable coherent Raman spectroscopy.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
14 02 2023
Historique:
received: 09 01 2023
accepted: 07 02 2023
entrez: 14 2 2023
pubmed: 15 2 2023
medline: 17 2 2023
Statut: epublish

Résumé

Vibrational spectroscopies offer great potential for standoff detection of chemical and biological warfare agents, avoiding contamination to the operator and equipment. Among them, particularly promising is Coherent anti-Stokes Raman scattering (CARS) spectroscopy, using synchronized pump/Stokes laser pulses to set up a vibrational coherence of target molecules at a laser focus, which is read by further interaction with a probe pulse, resulting in the emission of a coherent beam detectable at a distance. CARS has previously demonstrated the capability to detect bacterial spores based on the Raman spectrum of the characteristic molecule calcium dipicolinate (CaDPA); however, a complex and bulky laser technology, which is only suitable for a laboratory environment, was employed. Here we develop a broadband CARS setup based on a compact, industrial grade ytterbium laser system. We demonstrate high signal-to-noise ratio detection of Bacillus atrophaeus spores at a concentration of 10

Identifiants

pubmed: 36788326
doi: 10.1038/s41598-023-29589-7
pii: 10.1038/s41598-023-29589-7
pmc: PMC9929236
doi:

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

2634

Informations de copyright

© 2023. The Author(s).

Références

Anal Chem. 2021 Jan 12;93(1):417-429
pubmed: 33350812
Analyst. 2012 Aug 21;137(16):3683-9
pubmed: 22763367
Opt Lett. 2004 Dec 15;29(24):2923-5
pubmed: 15645825
Anal Chim Acta. 2007 Apr 4;588(1):108-16
pubmed: 17386799
Opt Lett. 2007 Jun 15;32(12):1725-7
pubmed: 17572760
Appl Spectrosc. 2005 Jun;59(6):769-75
pubmed: 16053543
Proc Natl Acad Sci U S A. 2009 Nov 17;106(46):19334-9
pubmed: 19892742
J Chem Phys. 2014 Jan 14;140(2):024316
pubmed: 24437886
Opt Express. 2017 Mar 20;25(6):5832-5840
pubmed: 28381055
Appl Opt. 2009 Feb 1;48(4):B17-22
pubmed: 19183575
J Chem Phys. 2006 Jul 28;125(4):44502
pubmed: 16942151
Nature. 1990 Sep 20;347(6290):301-3
pubmed: 2205805
J Bacteriol. 2007 Jul;189(13):4681-7
pubmed: 17468248
Science. 2007 Apr 13;316(5822):265-8
pubmed: 17431177
Appl Spectrosc. 2008 Apr;62(4):353-63
pubmed: 18416891
Opt Express. 2019 Nov 11;27(23):32924-32937
pubmed: 31878368
Opt Express. 2020 Feb 17;28(4):4541-4549
pubmed: 32121688
J Appl Microbiol. 2008 Jul;105(1):68-77
pubmed: 18298528
Appl Spectrosc. 2012 Nov;66(11):1279-85
pubmed: 23146183
Anal Bioanal Chem. 2009 Sep;395(2):323-35
pubmed: 19633965
Spectrochim Acta A Mol Biomol Spectrosc. 2005 Aug;61(10):2281-7
pubmed: 16029850
Opt Lett. 2006 Jan 15;31(2):241-3
pubmed: 16441043
Spectrochim Acta A Mol Biomol Spectrosc. 2003 Aug;59(10):2391-407
pubmed: 12909150
Biomed Opt Express. 2012 Nov 1;3(11):2964-75
pubmed: 23162732
Opt Express. 2022 Apr 25;30(9):15376-15387
pubmed: 35473258
Anal Chem. 2003 Jul 15;75(14):3631-6
pubmed: 14570219
Proc Natl Acad Sci U S A. 2008 Jan 15;105(2):422-7
pubmed: 18184801
Appl Spectrosc. 2017 May;71(5):833-838
pubmed: 27340220

Auteurs

Nicola Coluccelli (N)

Dipartimento di Fisica-Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133, Milan, Italy. nicola.coluccelli@polimi.it.
Istituto di Fotonica e Nanotecnologie-CNR, Piazza Leonardo da Vinci 32, 20133, Milan, Italy. nicola.coluccelli@polimi.it.

Gianluca Galzerano (G)

Istituto di Fotonica e Nanotecnologie-CNR, Piazza Leonardo da Vinci 32, 20133, Milan, Italy.

Paolo Laporta (P)

Dipartimento di Fisica-Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133, Milan, Italy.
Istituto di Fotonica e Nanotecnologie-CNR, Piazza Leonardo da Vinci 32, 20133, Milan, Italy.

Kelly Curtis (K)

Defence Science and Technology Laboratory, Porton Down, Salisbury, UK.

Claire L Lonsdale (CL)

Defence Science and Technology Laboratory, Porton Down, Salisbury, UK.

Debbie Padgen (D)

Defence Science and Technology Laboratory, Porton Down, Salisbury, UK.

Christopher R Howle (CR)

Defence Science and Technology Laboratory, Porton Down, Salisbury, UK.

Giulio Cerullo (G)

Dipartimento di Fisica-Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133, Milan, Italy.
Istituto di Fotonica e Nanotecnologie-CNR, Piazza Leonardo da Vinci 32, 20133, Milan, Italy.

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