New Opportunities in Metal-Organic Framework Catalysis: From Bifunctional to Frustrated Lewis Pairs Catalysis.

bifunctional acid-base solid frustrated Lewis pairs heterogeneous catalysis hydrogenation catalysis metal-organic frameworks

Journal

Chemistry (Weinheim an der Bergstrasse, Germany)
ISSN: 1521-3765
Titre abrégé: Chemistry
Pays: Germany
ID NLM: 9513783

Informations de publication

Date de publication:
06 Jul 2023
Historique:
received: 22 12 2022
medline: 10 7 2023
pubmed: 2 5 2023
entrez: 2 5 2023
Statut: ppublish

Résumé

This article highlights novel prospects for metal-organic frameworks (MOFs) in heterogeneous catalysis as having frustrated Lewis acid-base pairs (FLPs) or as bifunctional acid-base solid catalysts able to activate molecular hydrogen. Starting from the extensive application MOFs as Lewis acid and Lewis base catalysts, this article uses catalytic hydrogenation to briefly summarize the efforts made to heterogenize boron and amine in MOFs to mimic molecular FLP systems. The core of this concept is based on recent findings which demonstrate the ability of two commonly used MOFs, namely UiO-66 and MIL-101, to catalyze the selective hydrogenation of polar double X=Y bonds at moderate H

Identifiants

pubmed: 37130093
doi: 10.1002/chem.202204016
doi:

Substances chimiques

Metal-Organic Frameworks 0
Lewis Acids 0
Amines 0
Boron N9E3X5056Q

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

e202204016

Subventions

Organisme : Ministerio de Ciencia e Innovación
ID : Severo Ochoa CEX2021-1230-S and PDI2021-126071-OB-C21
Organisme : Ministerio de Ciencia e Innovación
ID : Maria Zambrano.
Organisme : Generalitat Valenciana
ID : Prometeo 2021-038

Informations de copyright

© 2023 Wiley-VCH GmbH.

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Auteurs

Amarajothi Dhakshinamoorthy (A)

Departamento de Química, Universitat Politècnica de València, Camino de Vera, s/n, 46022, Valencia, Spain.
School of Chemistry, Madurai Kamaraj University, Madurai, 625021, Tamil Nadu, India.

Abdullah M Asiri (AM)

Center of Excellence in Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia.

Hermenegildo Garcia (H)

Center of Excellence in Advanced Materials Research, King Abdulaziz University, Jeddah, Saudi Arabia.
Instituto Universitario de Tecnología Química, Consejo Superior de Investigaciones Científicas, Universitat Politecnica de Valencia, Av. De los Naranjos s/n, Valencia, 46022, Spain.

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