Anodic Cyclizations and Umpolung Reactions Involving Imines.

Cyclization Imines Oxidation-Reduction

Journal

Organic letters
ISSN: 1523-7052
Titre abrégé: Org Lett
Pays: United States
ID NLM: 100890393

Informations de publication

Date de publication:
09 Jun 2023
Historique:
medline: 12 6 2023
pubmed: 30 5 2023
entrez: 30 5 2023
Statut: ppublish

Résumé

Recent discoveries that anodic cyclization reactions rely heavily on the success of a second electron oxidation downstream of the cyclization suggest that this second electron oxidation step can be used to channel a reaction down new synthetic pathways. Here we describe one such application that reverses the normal reactivity of an imine group and sets the stage for the asymmetric synthesis of cyclic amines by anodic cyclization.

Identifiants

DOI: 10.1021/acs.orglett.3c01399 PMID: 37249221
pubmed: 37249221
doi: 10.1021/acs.orglett.3c01399
doi:

Substances chimiques

Imines 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

4135-4139

Auteurs

Zach Medcalf (Z)

Department of Chemistry, Washington University in Saint Louis, Saint Louis, Missouri 63130, United States.

Essence G Redd (EG)

Department of Chemistry, Texas State University, San Marco, Texas 78666, United States.

Jaemyeong Oh (J)

Department of Chemistry, Texas State University, San Marco, Texas 78666, United States.

Chang Ji (C)

Department of Chemistry, Texas State University, San Marco, Texas 78666, United States.

Kevin D Moeller (KD)

Department of Chemistry, Washington University in Saint Louis, Saint Louis, Missouri 63130, United States.
ORCID: 0000-0002-3893-5923

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Classifications MeSH

questionsmedicales.fr › Métabolisme › Cyclisation › Anodic Cyclizations and Umpolung Reactions...
questionsmedicales.fr › Composés chimiques organiques › Imines › Anodic Cyclizations and Umpolung Reactions...
questionsmedicales.fr › Métabolisme › Métabolisme énergétique › Oxydoréduction › Anodic Cyclizations and Umpolung Reactions...