Structural basis of sequence-specific cytosine deamination by double-stranded DNA deaminase toxin DddA.


Journal

Nature structural & molecular biology
ISSN: 1545-9985
Titre abrégé: Nat Struct Mol Biol
Pays: United States
ID NLM: 101186374

Informations de publication

Date de publication:
08 2023
Historique:
received: 04 09 2022
accepted: 12 06 2023
medline: 23 8 2023
pubmed: 18 7 2023
entrez: 17 7 2023
Statut: ppublish

Résumé

The interbacterial deaminase toxin DddA catalyzes cytosine-to-uracil conversion in double-stranded (ds) DNA and enables CRISPR-free mitochondrial base editing, but the molecular mechanisms underlying its unique substrate selectivity have remained elusive. Here, we report crystal structures of DddA bound to a dsDNA substrate containing the 5'-TC target motif. These structures show that DddA binds to the minor groove of a sharply bent dsDNA and engages the target cytosine extruded from the double helix. DddA Phe1375 intercalates in dsDNA and displaces the 5' (-1) thymine, which in turn replaces the target (0) cytosine and forms a noncanonical T-G base pair with the juxtaposed guanine. This tandem displacement mechanism allows DddA to locate a target cytosine without flipping it into the active site. Biochemical experiments demonstrate that DNA base mismatches enhance the DddA deaminase activity and relax its sequence selectivity. On the basis of the structural information, we further identified DddA mutants that exhibit attenuated activity or altered substrate preference. Our studies may help design new tools useful in genome editing or other applications.

Identifiants

pubmed: 37460895
doi: 10.1038/s41594-023-01034-3
pii: 10.1038/s41594-023-01034-3
pmc: PMC10442228
doi:

Substances chimiques

Cytosine 8J337D1HZY
DNA 9007-49-2
Uracil 56HH86ZVCT
Cytidine Deaminase EC 3.5.4.5

Types de publication

Journal Article Research Support, U.S. Gov't, Non-P.H.S. Research Support, N.I.H., Extramural

Langues

eng

Sous-ensembles de citation

IM

Pagination

1153-1159

Subventions

Organisme : NCI NIH HHS
ID : P01 CA234228
Pays : United States
Organisme : NIGMS NIH HHS
ID : R35 GM118047
Pays : United States
Organisme : NCRR NIH HHS
ID : S10 RR029205
Pays : United States
Organisme : NIGMS NIH HHS
ID : P30 GM124165
Pays : United States

Informations de copyright

© 2023. The Author(s).

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Auteurs

Lulu Yin (L)

Department of Biochemistry, Molecular Biology, and Biophysics, University of Minnesota, Minneapolis, MN, USA.
Institute for Molecular Virology, University of Minnesota, Minneapolis, MN, USA.
Masonic Cancer Center, University of Minnesota, Minneapolis, MN, USA.

Ke Shi (K)

Department of Biochemistry, Molecular Biology, and Biophysics, University of Minnesota, Minneapolis, MN, USA.
Institute for Molecular Virology, University of Minnesota, Minneapolis, MN, USA.
Masonic Cancer Center, University of Minnesota, Minneapolis, MN, USA.

Hideki Aihara (H)

Department of Biochemistry, Molecular Biology, and Biophysics, University of Minnesota, Minneapolis, MN, USA. aihar001@umn.edu.
Institute for Molecular Virology, University of Minnesota, Minneapolis, MN, USA. aihar001@umn.edu.
Masonic Cancer Center, University of Minnesota, Minneapolis, MN, USA. aihar001@umn.edu.

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Classifications MeSH