Laminarin-modulated osmium nanozymes with high substrate-affinity and selective peroxidase-like behavior engineered colorimetric assay for hydroxyl radical scavenging capacity estimation.
Colorimetric assay
Hydroxyl radical scavenging capacity
Laminarin
Nanozyme
Osmium nanoclusters
Peroxidase-like
Journal
Mikrochimica acta
ISSN: 1436-5073
Titre abrégé: Mikrochim Acta
Pays: Austria
ID NLM: 7808782
Informations de publication
Date de publication:
27 Jul 2024
27 Jul 2024
Historique:
received:
29
05
2024
accepted:
13
07
2024
medline:
28
7
2024
pubmed:
28
7
2024
entrez:
27
7
2024
Statut:
epublish
Résumé
Hydroxyl radical (·OH) scavenging capacity (HOSC) estimation is essential for evaluating antioxidants, natural extracts, or drugs against clinical diseases. While nanozymes offer advantages in related applications, they still face limitations in activity and selectivity. In response, this work showcases the fabrication of laminarin-modulated osmium (laminarin-Os) nanoclusters (1.45 ± 0.05 nm), functioning as peroxidase-like nanozymes within a colorimetric assay tailored for rational HOSC estimation. This study validates both the characterization and remarkable stability of laminarin-Os. By leveraging the abundant surface negative charges of laminarin-Os and the surface hydroxyls of laminarin, oxidation reactions are facilitated, augmenting laminarin-Os's affinity for 3,3',5,5'-tetramethylbenzidine (TMB) (K
Identifiants
pubmed: 39066796
doi: 10.1007/s00604-024-06571-2
pii: 10.1007/s00604-024-06571-2
doi:
Substances chimiques
Glucans
0
Benzidines
0
laminaran
9008-22-4
Hydroxyl Radical
3352-57-6
Free Radical Scavengers
0
3,3',5,5'-tetramethylbenzidine
3B3T5CB8EO
Osmium
2E7M255OPY
Peroxidase
EC 1.11.1.7
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Pagination
488Subventions
Organisme : Joint Funds for the Innovation of Science and Technology, Fujian Province
ID : 2023Y9226
Organisme : Natural Science Foundation of Fujian Province
ID : 2022J01271
Organisme : Introduced High-Level Talent Team Project of Quanzhou City
ID : 2023CT008
Organisme : Science and Technology Program of Quanzhou
ID : 2024NY069
Informations de copyright
© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.
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