Exploring Border Conditions for Spontaneous Emergence of Chirality in Allylboration of 1,2,3-Triazolic Aldehydes.

Aldehydes / chemistry Stereoisomerism Triazoles / chemistry Thermodynamics Boranes / chemistry Molecular Structure
1,2,3-triazole derivatives DFT (Density Functional Theory) computations allylboration disperse interactions spontaneous emergence of chirality stereoselective reactions

Journal

International journal of molecular sciences
ISSN: 1422-0067
Titre abrégé: Int J Mol Sci
Pays: Switzerland
ID NLM: 101092791

Informations de publication

Date de publication:
20 Oct 2024
Historique:
received: 02 09 2024
revised: 15 10 2024
accepted: 18 10 2024
medline: 26 10 2024
pubmed: 26 10 2024
entrez: 26 10 2024
Statut: epublish

Résumé

A case of spontaneous chirality generation was observed during a synthetic project studying the allylboration of 1,2,3-triazolic aldehydes. Here, we present computational studies supported by experimental findings targeting the elucidation of border conditions required for the observation of spontaneous chirality generation in the reaction of 1-Ar-1

Identifiants

DOI: 10.3390/ijms252011273 PMID: 39457055
pubmed: 39457055
pii: ijms252011273
doi: 10.3390/ijms252011273
pii:
doi:

Substances chimiques

Aldehydes 0
Triazoles 0
Boranes 0

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Subventions

Organisme : Russian Science Foundation
ID : #22-13-00275

Auteurs

Oleg A Mikhailov (OA)

N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, Russia.

Mikhail E Gurskii (ME)

N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, Russia.

Almira R Kurbangalieva (AR)

Biofunctional Chemistry Laboratory, A. Butlerov Institute of Chemistry, Kazan Federal University, 18 Kremlyovskaya Street, 420008 Kazan, Russia.
ORCID: 0000-0002-2436-7427

Ilya D Gridnev (ID)

N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prosp. 47, 119991 Moscow, Russia.
ORCID: 0000-0002-6711-9036

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Aldéhydes › Exploring Border Conditions for Spontaneous...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes de chimie organique › Isomérie › Stéréoisomérie › Exploring Border Conditions for Spontaneous...
questionsmedicales.fr › Composés hétérocycliques › Composés hétéromonocycliques › Azoles › Triazoles › Exploring Border Conditions for Spontaneous...
questionsmedicales.fr › Phénomènes physiques › Thermodynamique › Exploring Border Conditions for Spontaneous...
questionsmedicales.fr › Composés chimiques organiques › Composés du bore › Boranes › Exploring Border Conditions for Spontaneous...
questionsmedicales.fr › Phénomènes chimiques › Structure moléculaire › Exploring Border Conditions for Spontaneous...