A suite of kinetically superior AEP ligases can cyclise an intrinsically disordered protein.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
25 07 2019
Historique:
received: 24 05 2019
accepted: 11 07 2019
entrez: 27 7 2019
pubmed: 28 7 2019
medline: 22 10 2020
Statut: epublish

Résumé

Asparaginyl endopeptidases (AEPs) are a class of enzymes commonly associated with proteolysis in the maturation of seed storage proteins. However, a subset of AEPs work preferentially as peptide ligases, coupling release of a leaving group to formation of a new peptide bond. These "ligase-type" AEPs require only short recognition motifs to ligate a range of targets, making them useful tools in peptide and protein engineering for cyclisation of peptides or ligation of separate peptides into larger products. Here we report the recombinant expression, ligase activity and cyclisation kinetics of three new AEPs from the cyclotide producing plant Oldenlandia affinis with superior kinetics to the prototypical recombinant AEP ligase OaAEP1

Identifiants

pubmed: 31346249
doi: 10.1038/s41598-019-47273-7
pii: 10.1038/s41598-019-47273-7
pmc: PMC6658665
doi:

Substances chimiques

Antigens, Protozoan 0
Intrinsically Disordered Proteins 0
Plant Proteins 0
Protozoan Proteins 0
Recombinant Proteins 0
merozoite surface protein 2, Plasmodium 0
Cysteine Endopeptidases EC 3.4.22.-
asparaginylendopeptidase EC 3.4.22.34
Ligases EC 6.-

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

10820

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Auteurs

Karen S Harris (KS)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Rosemary F Guarino (RF)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Ravindu S Dissanayake (RS)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Pedro Quimbar (P)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Owen C McCorkelle (OC)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Simon Poon (S)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Quentin Kaas (Q)

Institute for Molecular Bioscience, The University of Queensland, Brisbane, QLD, 4072, Australia.

Thomas Durek (T)

Institute for Molecular Bioscience, The University of Queensland, Brisbane, QLD, 4072, Australia.

Edward K Gilding (EK)

Institute for Molecular Bioscience, The University of Queensland, Brisbane, QLD, 4072, Australia.

Mark A Jackson (MA)

Institute for Molecular Bioscience, The University of Queensland, Brisbane, QLD, 4072, Australia.

David J Craik (DJ)

Institute for Molecular Bioscience, The University of Queensland, Brisbane, QLD, 4072, Australia.

Nicole L van der Weerden (NL)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Robin F Anders (RF)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia.

Marilyn A Anderson (MA)

La Trobe Institute for Molecular Science, Melbourne, Vic., 3086, Australia. m.anderson@latrobe.edu.au.

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Classifications MeSH