Achieving Site-Selectivity for C-H Activation Processes Based on Distance and Geometry: A Carpenter's Approach.
Journal
Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056
Informations de publication
Date de publication:
17 06 2020
17 06 2020
Historique:
pubmed:
22
5
2020
medline:
14
4
2021
entrez:
22
5
2020
Statut:
ppublish
Résumé
The ability to differentiate between highly similar C-H bonds in a given molecule remains a fundamental challenge in organic chemistry. In particular, the lack of sufficient steric and electronic differences between C-H bonds located distal to functional groups has prevented the development of site-selective catalysts with broad scope. An emerging approach to circumvent this obstacle is to utilize the
Identifiants
pubmed: 32437604
doi: 10.1021/jacs.0c04074
pmc: PMC7485751
mid: NIHMS1625960
doi:
Substances chimiques
Alcohols
0
Amines
0
Carboxylic Acids
0
Organophosphonates
0
Sulfinic Acids
0
Transition Elements
0
Types de publication
Journal Article
Research Support, N.I.H., Extramural
Research Support, Non-U.S. Gov't
Research Support, U.S. Gov't, Non-P.H.S.
Review
Langues
eng
Sous-ensembles de citation
IM
Pagination
10571-10591Subventions
Organisme : NIGMS NIH HHS
ID : R01 GM102265
Pays : United States
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