Phallac acids A and B, new sesquiterpenes from the fruiting bodies of Phallus luteus.


Journal

The Journal of antibiotics
ISSN: 1881-1469
Titre abrégé: J Antibiot (Tokyo)
Pays: England
ID NLM: 0151115

Informations de publication

Date de publication:
10 2020
Historique:
received: 12 03 2020
accepted: 08 05 2020
pubmed: 31 5 2020
medline: 20 2 2021
entrez: 31 5 2020
Statut: ppublish

Résumé

Phallus luteus (Phallaceae), previously known as Dictyophora indusiata, is an edible and medicinal mushroom. As part of a continuing project to discover structurally and/or biologically novel natural products from wild mushrooms, we aimed to perform a chemical investigation of the methanol extract of P. luteus combined with a liquid chromatography-mass spectrometry-guided analysis coupled to an in-house UV spectral library. Two new sesquiterpenes, phallac acids A (1) and B (2), were isolated and determined. The chemical structure of the new natural products was unambiguously determined using a combination of 1D and 2D NMR and high-resolution electrospray ionization mass spectrometry data. To our knowledge, this is the first study to report linear sesquiterpene carboxylic acids from P. luteus. The new compounds were evaluated for α-glucosidase inhibitory activities where phallac acid B (2) showed α-glucosidase inhibitory potential (IC

Identifiants

pubmed: 32472053
doi: 10.1038/s41429-020-0328-z
pii: 10.1038/s41429-020-0328-z
doi:

Substances chimiques

Glycoside Hydrolase Inhibitors 0
Sesquiterpenes 0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

729-732

Références

Kasuya T. Phallus luteus comb, nov., a new taxonomic treatment of a tropical phalloid fungus. Mycotaxon. 2008;106:7–13.
Ker YB, Chen KC, Peng CC, Hsieh CL, Peng RY. Structural characteristics and antioxidative capability of the soluble polysaccharides present in Dictyophora indusiata (Vent. Ex Pers.) Fish Phallaceae. eCAM. 2011;2011:396013.
pubmed: 21799678
Sitinjak RR. The nutritional content of the mushroom Phallus indusiatus Vent, which grows in the cocoa plantation, Gaperta-Ujung, Medan. Pharm Chem. 2017;9:44–7.
Sharma VK, Choi J, Sharma N, Choi M, Seo SY. In vitro anti-tyrosinase activity of 5-(Hydroxymethyl)-2-furfural isolated from Dictyophora indusiate. Phytother Res. 2004;18:841–4.
doi: 10.1002/ptr.1428
Mau JL, Lin HC, Song SF. Antioxidant properties of several specialty mushrooms. Food Res Int. 2002;35:519–26.
doi: 10.1016/S0963-9969(01)00150-8
Ishiyama D, et al. Monoterpene-alcohols from a mushroom Dictyophora indusiata. Phytochemistry. 1999;50:1053–6.
doi: 10.1016/S0031-9422(98)00630-X
Kawagishi H, et al. Dictyophorines A and B, two stimulators of NGF-synthesis from the mushroom Dictyophora indusiata. Phytochemistry. 1997;45:1203–5.
doi: 10.1016/S0031-9422(97)00144-1
Lee IK, et al. Dictyoquinazols A, B, and C, new neuroprotective compounds from the mushroom Dictyophora indusiata. J Nat Prod. 2002;65:1769–72.
doi: 10.1021/np020163w
Lee SR, et al. Pantheric acids A-C from a Poisonous Mushroom, Amanita pantherina Promote Lipid Accumulation in Adipocytes. J Nat Prod. 2019;82:3489–93.
doi: 10.1021/acs.jnatprod.9b00782
Lee SR, Seok S, Ryoo R, Choi SU, Kim KH. Macrocyclic trichothecene mycotoxins from a deadly poisonous mushroom Podostroma cornu-damae. J Nat Prod. 2019;82:122–8.
doi: 10.1021/acs.jnatprod.8b00823
Lee S, et al. Cytotoxic constituents from the sclerotia of Poria cocos against human lung adenocarcinoma cells by inducing mitochondrial apoptosis. Cells. 2018;7:116.
doi: 10.3390/cells7090116
So HM, et al. Bioactivity evaluations of betulin identified from the bark of Betula platyphylla var. japonica for cancer therapy. Arch Pharmacal Res. 2018;41:815–22.
doi: 10.1007/s12272-018-1064-9
Baek SC, et al. LC/MS-based analysis of bioactive compounds from the bark of Betula platyphylla var. japonica and their effects on regulation of adipocyte and osteoblast differentiation. Nat Prod Sci. 2018;24:235–40.
doi: 10.20307/nps.2018.24.4.235
Hwang JY, You MJ, Oh DC, Oh KB, Shin J. New meroterpenoids from a Penicillium sp. Fungus. Nat Prod Sci. 2018;24:253–8.
doi: 10.20307/nps.2018.24.4.253
Yang H, et al. Plant-derived juvenile hormone III analogues and other sesquiterpenes from the stem bark of Cananga latifolia. Phytochemistry. 2013;94:277–83.
doi: 10.1016/j.phytochem.2013.06.010
Nkunya MH, Jonker SA, Makangara JJ, Waibel R, Achenbach H. Aporphinoid alkaloids and other constituents from Lettowianthus stellatus. Phytochemistry. 2000;53:1067–73.
doi: 10.1016/S0031-9422(00)00012-1
Thao NP, et al. α-Amylase and α-glucosidase inhibitory activities of chemical constituents from Wedelia chinensis (Osbeck.) Merr. Leaves. J Anal Methods Chem. 2018;2018:2794904.
doi: 10.1155/2018/2794904
Zhao JQ, et al. Three new monoterpene glycosides from Sibiraea laevigata (L.) Maxim. Phytochem Lett. 2017;19:176–80.
doi: 10.1016/j.phytol.2017.01.002
Wang K, et al. A novel class of α-glucosidase and HMG-CoA reductase inhibitors from Ganoderma leucocontextum and the anti-diabetic properties of ganomycin I in KK-A
doi: 10.1016/j.ejmech.2016.11.015
Valdes M, Calzada F, Mendieta-Wejebe J. Structure-activity relationship study of acyclic terpenes in blood glucose levels: Potential α-glucosidase and sodium glucose cotransporter (SGLT-1) inhibitors. Molecules. 2019;24:E4020.
doi: 10.3390/molecules24224020

Auteurs

Seoung Rak Lee (SR)

Natural Product Research Laboratory, School of Pharmacy, Sungkyunkwan University, Suwon, 16419, Republic of Korea.

Dahae Lee (D)

College of Korean Medicine, Gachon University, Seongnam, 13120, Republic of Korea.

Bum Soo Lee (BS)

Natural Product Research Laboratory, School of Pharmacy, Sungkyunkwan University, Suwon, 16419, Republic of Korea.

Rhim Ryoo (R)

Special Forest Products Division, Forest Bioresources Department, National Institute of Forest Science, Suwon, 16631, Republic of Korea.

Changhyun Pang (C)

School of Chemical Engineering, Sungkyunkwan University, Suwon, 16419, Republic of Korea.

Ki Sung Kang (KS)

College of Korean Medicine, Gachon University, Seongnam, 13120, Republic of Korea.

Ki Hyun Kim (KH)

Natural Product Research Laboratory, School of Pharmacy, Sungkyunkwan University, Suwon, 16419, Republic of Korea. khkim83@skku.edu.

Articles similaires

Fucosyltransferases Drug Repositioning Molecular Docking Simulation Molecular Dynamics Simulation Humans
Nitriles Tensile Strength Materials Testing Gloves, Protective Product Packaging
Klebsiella pneumoniae Volatile Organic Compounds Metabolomics Ion Mobility Spectrometry Bacterial Proteins

The conformational landscape of fold-switcher KaiB is tuned to the circadian rhythm timescale.

Hannah K Wayment-Steele, Renee Otten, Warintra Pitsawong et al.
1.00
Rhodobacter sphaeroides Bacterial Proteins Circadian Rhythm Protein Folding Protein Conformation

Classifications MeSH