Cu-BTC Functional Microdevices as Smart Tools for Capture and Preconcentration of Nerve Agents.

Adsorption Copper / chemistry Metal-Organic Frameworks / chemistry Nerve Agents / analysis Particle Size Potentiometry Surface Properties Tricarboxylic Acids / chemistry
co-adsorbed water vapor copper-modified glass substrates integration of metal−organic framework films microfabrication nerve agents capture threshold current density

Journal

ACS applied materials & interfaces
ISSN: 1944-8252
Titre abrégé: ACS Appl Mater Interfaces
Pays: United States
ID NLM: 101504991

Informations de publication

Date de publication:
23 Sep 2020
Historique:
pubmed: 23 6 2020
medline: 6 3 2021
entrez: 23 6 2020
Statut: ppublish

Résumé

Cu-based metal-organic framework (MOF) microdevices are applied in sampling and preconcentration of nerve agents (NAs) diluted in gaseous streams. An in situ electrochemical-assisted synthesis of a Cu-benzene-1,3,5-tricarboxylate (BTC) thick film is carried out to functionalize a Cu-modified glass substrate. This simple, rapid, reproducible, and easy-to-integrate MOF synthesis approach enables the microfabrication of functional micro-preconcentrators with a large Brunauer-Emmett-Teller (BET) surface area (above 2000 cm

Identifiants

DOI: 10.1021/acsami.0c07364 PMID: 32568508
pubmed: 32568508
doi: 10.1021/acsami.0c07364
doi:

Substances chimiques

Metal-Organic Frameworks 0
Nerve Agents 0
Tricarboxylic Acids 0
Copper 789U1901C5

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

42622-42633

Auteurs

F Almazán (F)

Department of Chemical & Environmental Engineering, Univ. Zaragoza, Campus Rı́o Ebro, Zaragoza 50018, Spain.
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain.
ORCID: 0000-0001-5063-2987

M A Urbiztondo (MA)

Department of Chemical & Environmental Engineering, Univ. Zaragoza, Campus Rı́o Ebro, Zaragoza 50018, Spain.
Centro Universitario de la Defensa de Zaragoza, Carretera Huesca s/n, 50090 Zaragoza, Spain.
ORCID: 0000-0002-4931-1358

P Serra-Crespo (P)

Applied Radiation and Isotopes, Department of Radiation Science and Technology, Faculty of Applied Sciences, Technical University Delft, Mekelweg 15, 2629 JB Delft, the Netherlands.
ORCID: 0000-0002-5106-0527

B Seoane (B)

Catalysis Engineering, Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ Delft, The Netherlands.
ORCID: 0000-0002-9100-4773

J Gascon (J)

Catalysis Engineering, Department of Chemical Engineering, Delft University of Technology, Van der Maasweg 9, 2629 HZ Delft, The Netherlands.
Advanced Catalytic Materials, KAUST Catalysis Center, King Abdullah University of Science and Technology, 23955 Thuwal, Saudi Arabia.
ORCID: 0000-0001-7558-7123

J Santamaría (J)

Department of Chemical & Environmental Engineering, Univ. Zaragoza, Campus Rı́o Ebro, Zaragoza 50018, Spain.
Networking Research Center on Bioengineering, Biomaterials and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain.
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain.
ORCID: 0000-0002-8701-9745

M P Pina (MP)

Department of Chemical & Environmental Engineering, Univ. Zaragoza, Campus Rı́o Ebro, Zaragoza 50018, Spain.
Networking Research Center on Bioengineering, Biomaterials and Nanomedicine, CIBER-BBN, 28029 Madrid, Spain.
Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain.
ORCID: 0000-0001-9897-6527

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Classifications MeSH

questionsmedicales.fr › Phénomènes chimiques › Adsorption › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Cuivre › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Structures macromoléculaires › Réseaux organométalliques › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Agents neurotoxiques › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Phénomènes chimiques › Taille de particule › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Techniques d'investigation › Techniques électrochimiques › Potentiométrie › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Phénomènes chimiques › Propriétés de surface › Cu-BTC Functional Microdevices as Smart Tools...
questionsmedicales.fr › Composés chimiques organiques › Acides carboxyliques › Acides acycliques › Triacides carboxyliques › Cu-BTC Functional Microdevices as Smart Tools...