Inverse relation between structural flexibility and IgE reactivity of Cor a 1 hazelnut allergens.


Journal

Scientific reports
ISSN: 2045-2322
Titre abrégé: Sci Rep
Pays: England
ID NLM: 101563288

Informations de publication

Date de publication:
18 02 2021
Historique:
received: 03 12 2020
accepted: 05 02 2021
entrez: 19 2 2021
pubmed: 20 2 2021
medline: 15 12 2021
Statut: epublish

Résumé

A major proportion of allergic reactions to hazelnuts (Corylus avellana) are caused by immunologic cross-reactivity of IgE antibodies to pathogenesis-related class 10 (PR-10) proteins. Intriguingly, the four known isoforms of the hazelnut PR-10 allergen Cor a 1, denoted as Cor a 1.0401-Cor a 1.0404, share sequence identities exceeding 97% but possess different immunologic properties. In this work we describe the NMR solution structures of these proteins and provide an in-depth study of their biophysical properties. Despite sharing highly similar three-dimensional structures, the four isoforms exhibit remarkable differences regarding structural flexibility, hydrogen bonding and thermal stability. Our experimental data reveal an inverse relation between structural flexibility and IgE-binding in ELISA experiments, with the most flexible isoform having the lowest IgE-binding potential, while the isoform with the most rigid backbone scaffold displays the highest immunologic reactivity. These results point towards a significant entropic contribution to the process of antibody binding.

Identifiants

pubmed: 33603065
doi: 10.1038/s41598-021-83705-z
pii: 10.1038/s41598-021-83705-z
pmc: PMC7892832
doi:

Substances chimiques

Allergens 0
Antigens, Plant 0
Plant Proteins 0
Protein Isoforms 0
Immunoglobulin E 37341-29-0

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

4173

Subventions

Organisme : Austrian Science Fund FWF
ID : P 30737
Pays : Austria

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Auteurs

Sebastian Führer (S)

Institute of Organic Chemistry and Center for Molecular Biosciences Innsbruck (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria.

Anna S Kamenik (AS)

Institute of General, Inorganic and Theoretical Chemistry and Center for Molecular Biosciences Innsbruck (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria.

Ricarda Zeindl (R)

Institute of Organic Chemistry and Center for Molecular Biosciences Innsbruck (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria.

Bettina Nothegger (B)

Department of Dermatology, Venerology and Allergology, Medical University of Innsbruck, Anichstraße 35, 6020, Innsbruck, Austria.

Florian Hofer (F)

Institute of General, Inorganic and Theoretical Chemistry and Center for Molecular Biosciences Innsbruck (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria.

Norbert Reider (N)

Department of Dermatology, Venerology and Allergology, Medical University of Innsbruck, Anichstraße 35, 6020, Innsbruck, Austria.

Klaus R Liedl (KR)

Institute of General, Inorganic and Theoretical Chemistry and Center for Molecular Biosciences Innsbruck (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria.

Martin Tollinger (M)

Institute of Organic Chemistry and Center for Molecular Biosciences Innsbruck (CMBI), University of Innsbruck, Innrain 80/82, 6020, Innsbruck, Austria. martin.tollinger@uibk.ac.at.

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Classifications MeSH