Recoverable Phospha-Michael Additions Catalyzed by a 4-
DMAP
adduct
catalysis
fluorous
long-chained
phospha-Michael
phosphite
pyridine
recoverable
thermomorphic
Journal
Molecules (Basel, Switzerland)
ISSN: 1420-3049
Titre abrégé: Molecules
Pays: Switzerland
ID NLM: 100964009
Informations de publication
Date de publication:
22 Feb 2021
22 Feb 2021
Historique:
received:
05
02
2021
revised:
18
02
2021
accepted:
19
02
2021
entrez:
6
3
2021
pubmed:
7
3
2021
medline:
10
4
2021
Statut:
epublish
Résumé
Phospha-Michael addition, which is the addition reaction of a phosphorus-based nucleophile to an acceptor-substituted unsaturated bond, certainly represents one of the most versatile and powerful tools for the formation of P-C bonds, since many different electrophiles and P nucleophiles can be combined with each other. This offers the possibility to access many diversely functionalized products. In this work, two kinds of basic pyridine-based organo-catalysts were used to efficiently catalyze phospha-Michael addition reactions, the 4-
Identifiants
pubmed: 33671544
pii: molecules26041159
doi: 10.3390/molecules26041159
pmc: PMC7926848
pii:
doi:
Substances chimiques
4-N,N-dimethylaminopyridine
0
Malonates
0
Methylamines
0
Organophosphonates
0
Organophosphorus Compounds
0
Phosphites
0
Pyridines
0
Salts
0
Saccharin
FST467XS7D
pyridine
NH9L3PP67S
dimethyl hydrogen phosphite
ST4TBO000H
Types de publication
Journal Article
Langues
eng
Sous-ensembles de citation
IM
Subventions
Organisme : Ministry of Science and Technology in Taiwan
ID : MOST 109-2113-M-027-003
Organisme : university joint grants
ID : NTUT-CGMH-109-07
Références
Angew Chem Int Ed Engl. 2000 Dec 15;39(24):4605-4607
pubmed: 11169685
Org Lett. 2006 May 11;8(10):2099-101
pubmed: 16671791
J Org Chem. 2005 Nov 25;70(24):10121-3
pubmed: 16292852
Molecules. 2016 Aug 24;21(9):
pubmed: 27563869
J Org Chem. 2000 Dec 29;65(26):8866-73
pubmed: 11149827
Molecules. 2021 Jan 13;26(2):
pubmed: 33450888
J Am Chem Soc. 2001 Nov 21;123(46):11490-1
pubmed: 11707132
Chem Commun (Camb). 2019 Nov 26;55(95):14259-14262
pubmed: 31656962
Chem Commun (Camb). 2011 Jul 7;47(25):7227-9
pubmed: 21623435
J Am Chem Soc. 2003 May 14;125(19):5861-72
pubmed: 12733927
J Org Chem. 1997 Apr 18;62(8):2414-2422
pubmed: 11671575
J Med Chem. 1989 Jul;32(7):1652-61
pubmed: 2661820
Org Lett. 2005 Mar 3;7(5):851-3
pubmed: 15727457
Angew Chem Int Ed Engl. 2005 Jun 27;44(26):4095-7
pubmed: 15900533