Simultaneous electrochemical recognition of tryptophan and penicillamine enantiomers based on MOF-modified β-CD.

Electrochemical Techniques Penicillamine Stereoisomerism Tryptophan beta-Cyclodextrins / chemistry
Chiral electrochemical sensor MOF Tryptophan and Penicillamine enantiomers β-Cyclodextrin

Journal

Carbohydrate polymers
ISSN: 1879-1344
Titre abrégé: Carbohydr Polym
Pays: England
ID NLM: 8307156

Informations de publication

Date de publication:
15 Aug 2022
Historique:
received: 31 12 2021
revised: 06 04 2022
accepted: 07 04 2022
entrez: 13 5 2022
pubmed: 14 5 2022
medline: 18 5 2022
Statut: ppublish

Résumé

Chiral recognition is of significant importance in the fields of chemical asymmetric synthesis and biological pharmaceutical research. In this work, an electrochemical chiral sensor with two kinds of chiral sites (chiral cavity for β-cyclodextrin and chiral skeleton for Ca-sacc/MeOH) by electrooxidation β-cyclodextrin onto Ca-sacc/MeOH was built. The proposed multichiral β-CD@Ca-sacc/MeOH/GCE can be used for recognition of tryptophan and penicillamine enantiomers simultaneously with wide linear range, low detection limits value, high repeatability and stability within the available electrochemical window. The strategy for integration multichiral sources is crucial to construct novel chiral platforms for simultaneous recognition of multiple chiral compounds in complicated chiral systems.

Identifiants

DOI: 10.1016/j.carbpol.2022.119474 PMID: 35550750
pubmed: 35550750
pii: S0144-8617(22)00379-4
doi: 10.1016/j.carbpol.2022.119474
pii:
doi:

Substances chimiques

beta-Cyclodextrins 0
Tryptophan 8DUH1N11BX
Penicillamine GNN1DV99GX

Types de publication

Journal Article

Langues

eng

Sous-ensembles de citation

IM

Pagination

119474

Informations de copyright

Copyright © 2022. Published by Elsevier Ltd.

Auteurs

Ying Hou (Y)

Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China.

Jiaqi Liang (J)

Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China.

Xuan Kuang (X)

Key Laboratory of Interfacial Reaction & Sensing Analysis in Universities of Shandong, School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China. Electronic address: chm_kuangx@ujn.edu.cn.

Rui Kuang (R)

College of Traffic Civil Engineering, Shandong Jiaotong University, Jinan 250023, China. Electronic address: kuangr1985@foxmail.com.

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Classifications MeSH

questionsmedicales.fr › Techniques d'investigation › Techniques électrochimiques › Simultaneous electrochemical recognition of...
questionsmedicales.fr › Acides aminés, peptides et protéines › Acides aminés › Acides aminés soufrés › Pénicillamine › Simultaneous electrochemical recognition of...
questionsmedicales.fr › Phénomènes chimiques › Phénomènes de chimie organique › Isomérie › Stéréoisomérie › Simultaneous electrochemical recognition of...
questionsmedicales.fr › Acides aminés, peptides et protéines › Acides aminés › Acides aminés essentiels › Tryptophane › Simultaneous electrochemical recognition of...
questionsmedicales.fr › Glucides › Polyosides › Glucanes › Amidon › Dextrine › Cyclodextrines › Cyclodextrines bêta › Simultaneous electrochemical recognition of...