One-Metal/Two-Ligand for Dual Activation Tandem Catalysis: Photoinduced Cu-Catalyzed Anti-hydroboration of Alkynes.

Alkynes / chemistry Boron / chemistry Catalysis Copper / chemistry Esters Ligands

Journal

Journal of the American Chemical Society
ISSN: 1520-5126
Titre abrégé: J Am Chem Soc
Pays: United States
ID NLM: 7503056

Informations de publication

Date de publication:
20 07 2022
Historique:
pubmed: 6 7 2022
medline: 22 7 2022
entrez: 5 7 2022
Statut: ppublish

Résumé

A dual catalyst system based on ligand exchange of two diphosphine ligands possessing different properties in a copper complex has been devised to merge metal- and photocatalytic activation modes. This strategy has been applied to the formal anti-hydroboration of activated internal alkynes via a tandem sequence in which Cu/Xantphos catalyzes the B

Identifiants

DOI: 10.1021/jacs.2c05805 PMID: 35786909 PMC: PMC9348838
pubmed: 35786909
doi: 10.1021/jacs.2c05805
pmc: PMC9348838
doi:

Substances chimiques

Alkynes 0
Esters 0
Ligands 0
Copper 789U1901C5
Boron N9E3X5056Q

Types de publication

Journal Article Research Support, Non-U.S. Gov't

Langues

eng

Sous-ensembles de citation

IM

Pagination

13006-13017

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Auteurs

Javier Corpas (J)

Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias, Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain.
ORCID: 0000-0002-8598-578X

Miguel Gomez-Mendoza (M)

Photoactivated Processes Unit, IMDEA Energy Institute, Technological Park of Mostoles, Avda. Ramón de la Sagra 3, 28935 Madrid, Spain.

Jonathan Ramírez-Cárdenas (J)

Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias, Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain.

Víctor A de la Peña O'Shea (VA)

Photoactivated Processes Unit, IMDEA Energy Institute, Technological Park of Mostoles, Avda. Ramón de la Sagra 3, 28935 Madrid, Spain.
ORCID: 0000-0001-5762-4787

Pablo Mauleón (P)

Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias, Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain.
Institute for Advanced Research in Chemical Sciences (IAdChem), UAM, 28049 Madrid, Spain.
ORCID: 0000-0002-3116-2534

Ramón Gómez Arrayás (R)

Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias, Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain.
Institute for Advanced Research in Chemical Sciences (IAdChem), UAM, 28049 Madrid, Spain.
ORCID: 0000-0002-5665-0905

Juan C Carretero (JC)

Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Facultad de Ciencias, Universidad Autónoma de Madrid (UAM), 28049 Madrid, Spain.
Institute for Advanced Research in Chemical Sciences (IAdChem), UAM, 28049 Madrid, Spain.
ORCID: 0000-0003-4822-5447

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Classifications MeSH

questionsmedicales.fr › Composés chimiques organiques › Hydrocarbures › Hydrocarbures acycliques › Alcynes › One-Metal/Two-Ligand for Dual Activation...
questionsmedicales.fr › Produits chimiques inorganiques › Éléments › Métalloïdes › Bore › One-Metal/Two-Ligand for Dual Activation...
questionsmedicales.fr › Phénomènes chimiques › Catalyse › One-Metal/Two-Ligand for Dual Activation...
questionsmedicales.fr › Produits chimiques inorganiques › Métaux › Métaux lourds › Cuivre › One-Metal/Two-Ligand for Dual Activation...
questionsmedicales.fr › Composés chimiques organiques › Acides carboxyliques › Esters › One-Metal/Two-Ligand for Dual Activation...
questionsmedicales.fr › Actions chimiques et utilisations › Utilisations spécialisées de produits chimiques › Produits chimiques de laboratoire › Ligands › One-Metal/Two-Ligand for Dual Activation...